Interfacial Dissolution, Diffusion, And Precipitation In A Viscous Multilayer

  The term "metamorphic differentiation" is usually restricted to the striking compositional layering that develops under certain circumstances between the hinge and limb regions of small-scale folds in foliated quartz/phyllosilicate rocks (Nicholson, 1966; Gray and Durney, 1979). Durney (1979) presented a model for its development. I re-analyze his model, but only for the early stage of fold development. As in the previous examples, one effect of dissolution, diffusion, and precipitation is to reduce the magnitude of the stress heterogeneity driving it. This leads to a qualitatively different result from the approximation in which this feedback is ignored, as in Durney’s treatment. Also, the stress distribution in such a multilayer is substantially different from the homogeneous stress that Durney assumed to estimate the rate of differentiation. The continuous layers of Durney’s model simulate the resistance of micas to bending, the likely importance of which was pointed out by Robin (1979).

The analysis follows the approach described in Johnson and Fletcher (1994). The multilayer is composed of layers of equal thickness, H, and viscosity h. The layers are separated by weak interfaces on which the slip rate, D{vs}, is set proportional to the resolved shear stress, sns, where s and n are local coordinates parallel and normal to the interface. Treating the interfaces as thin layers of thickness d* and viscosity h*,

D{vs}= (d*/h*)sns

(16)

The folding is vertically repetitive, with vertical axial planes, and occurs in shortening parallel to the mean orientation of the layers. Each interface is described by the locus, relative to the mean mid-plane of the layer,

z = H/2 + Acos(lx) (17)

where l = 2p/L, and L is the fold wavelength.

A measure of the rate of differentiation is the rate of growth in the thickness of the "saddle reefs" into which, in the model, the phase transported from the fold limbs precipitates. This is just the difference in normal velocities, D{vn}, evaluated at a hinge. The rate of thickening of the layer, excluding the saddle reef, at the hinge is –DxxH. The ratio -D{vn}/DxxH is a measure of the relative contributions of differentiation and layer deformation to the bulk rate of elongation along the hinge. From the analysis, I obtain

-D{vn}/DxxH

@ {(4hV0/H)W’’/[1 + (4hV0/H)W’’]}[(2 + q*/2)/(k2/3 + q*)](lA)2cos(2lx)

(18a)

where

W’’ = K(MV0/l2)/[K + (MV0/l2)] (18b)

k = 2pH/L is a dimensionless wavenumber, and q* = (h*/h)(H/d*). Comparison with the result for the pressure shadow suggests the identification of the Bayly Number with the quantity

B’’ = (4hV0/H)W’’ (19)

The expression (18a) thus also contains the factor [B’’/(1 + B’’)] times another dimensionless quantity containing q* and k, times the square of the maximum limb dip (in radians). As in the model for grain growth in a pressure shadow, the factor in B’’ embodies the principle of "saturation," with reduction in the driving term as B’’ increases. Thus, this factor varies between zero and unity as B’’ ranges from zero to infinity.

Since differentiation only enters to second-order in the limb dip, lA, it cannot enter into the wavelength-selection process. The rate of amplification is

dA/dt @ -DxxA - 2DxxA/(k2/6 + q*) (20)

In (20) and (18a), the exact result has been reduced to leading terms in k for k << 1, appropriate for large wavelength to layer thickness ratio, L/H >> 1. The approximations hold to terms ~ (lA)2, or up to limb-dips 10o - 20 o, above which both rates increase more slowly with limb-dip.

Using (18a) and (20), I have determined the thickness of "saddle reefs", or the amount of differentiation, as a function of limb dip. Consider the limiting case q* = 0, in which layer interfaces are frictionless. Let t = t/t* be a dimensionless time, with t* = 1/[(12/k2)|Dxx|]. In the approximation that the basic-state shortening need not be accounted for, appropriate if fold amplification is rapid, or t* << 1/|Dxx|, (20) yields

lA(t) = lA(0)et

(21)

where A(0) is the initial amplitude. If n(t) is the thickness of the saddle reef at the hinge, from (18a), (19), and (21)

d[n(t)/H]/dt = t*[D{vn}x = 0]/H = (½)[ B"/(1 +B")](lA)2 (22)

Integrating (22)

n(t)/H = (Ό)[B"/(1 + B")](lA)2 (23)

The thickness of the saddle reefs, or the amount of differentiation, is a function only of the Bayly Number and the limb dip. Consequently, B" can be estimated from field observations of n/H versus limb dip. The function (23) is plotted in Figure 3 for dips up to 45° , probably beyond where it gives a good approximation, for small (B" = 0.1), intermediate (B" = 1), and infinite values of B". The limb dip at which the approximation breaks down is that dip at which the folds no longer appear sinusoidal.

Figure 3. Amount of differentiation, as measured by the ratio of the thickness of a saddle reef to the layer thickness, n/H, as a function of limb dip in a symmetric crenulation, for Bayly Numbers B" = 0.1, 1, and ¥ .

 
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