Paraffinic hydrocarbons, or paraffin wax, are straight chained or branched
saturated organic compounds with the composition CnH2n+2
(Figure 4). The
purity of paraffin is a question of refining degree. The industrially used paraffin
and paraffin candles consists mostly of different molecular structures.
The macrocrystalline paraffin wax that we used chiefly consists of saturated,
normal C18- C30 hydrocarbons and smaller amounts of iso-alkanes
and cycloalkanes with a molecular weight between 250-450. At room temperature the paraffin
crystals are needle or plate shaped. A crystallographic change called allotropic
transition occurs in an equilibrium transition temperature range below the
melting point. The higher temperature phase is characterised by concentration of
defects and a molecular structure that can rotate along the long axis
(Kwang-Sup 1984). At still higher temperatures,
the stable structures are
systems of higher symmetry. The crystal structure depends on the molecular
composition of paraffin. C18-C26 has triclinic crystal
symmetry and C28-C36
has a monoclinic symmetry. Paraffin wax is usually described by the range of
its melt temperature, rather than chain length (e.g.
56o-58oC wax).
The rheological behaviour of paraffin wax has been investigated experimentally
by several authors (Mancktelow 1988,
Cobbold 1975, Neurath
&Smith 1982). All
investigated types of paraffin wax exhibit a power low creep behaviour over
the limited but experimentally relevant temperature range with
stress exponents of 2.6 (Cobbold 1975),
1.8 (Neurath & Smith 1982) and 2.4-4.1
(Mancktelow 1988).